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Beschreibung
Activity in any theoretical area is usually stimulated by new experimental techniques and the resulting opportunity of measuring phenomena that were previously inaccessible. Such has been the case in the area under consideration he re beginning about fifteen years aga when the possibility of studying chemical reactions in crossed molecular beams captured the imagination of physical chemists, for one could imagine investigating chemical kinetics at the same level of molecular detail that had previously been possible only in spectroscopic investigations of molecular stucture. This created an interest among chemists in scattering theory, the molecular level description of a bimolecular collision process. Many other new and also powerful experimental techniques have evolved to supplement the molecular be am method, and the resulting wealth of new information about chemical dynamics has generated the present intense activity in molecular collision theory. During the early years when chemists were first becoming acquainted with scattering theory, it was mainly a matter of reading the physics literature because scattering experiments have long been the staple of that field. It was natural to apply the approximations and models that had been developed for nuclear and elementary particle physics, and although some of them were useful in describing molecular collision phenomena, many were not.
Activity in any theoretical area is usually stimulated by new experimental techniques and the resulting opportunity of measuring phenomena that were previously inaccessible. Such has been the case in the area under consideration he re beginning about fifteen years aga when the possibility of studying chemical reactions in crossed molecular beams captured the imagination of physical chemists, for one could imagine investigating chemical kinetics at the same level of molecular detail that had previously been possible only in spectroscopic investigations of molecular stucture. This created an interest among chemists in scattering theory, the molecular level description of a bimolecular collision process. Many other new and also powerful experimental techniques have evolved to supplement the molecular be am method, and the resulting wealth of new information about chemical dynamics has generated the present intense activity in molecular collision theory. During the early years when chemists were first becoming acquainted with scattering theory, it was mainly a matter of reading the physics literature because scattering experiments have long been the staple of that field. It was natural to apply the approximations and models that had been developed for nuclear and elementary particle physics, and although some of them were useful in describing molecular collision phenomena, many were not.
Inhaltsverzeichnis
1. Classical Trajectory Methods in Molecular Collisions.- 2. Features of Potential Energy Surfaces and Their Effect on Collisions.- 3. Dynamics of Unimolecular Reactions.- 4. Semiclassical Methods in Molecular Collision Theory.- 5. Nonadiabatic Processes in Molecular Collisions.- 6. Statistical Approximations in Collision Theory.- 7. Thermodynamic Approach to Collision Processes.- Author Index.
Details
Erscheinungsjahr: 2013
Fachbereich: Physikalische Chemie
Genre: Chemie, Importe
Rubrik: Naturwissenschaften & Technik
Medium: Taschenbuch
Reihe: Modern Theoretical Chemistry
Inhalt: xv
380 S.
6 s/w Illustr.
380 p. 6 illus.
ISBN-13: 9781475706468
ISBN-10: 1475706464
Sprache: Englisch
Einband: Kartoniert / Broschiert
Redaktion: Miller, W.
Herausgeber: W Miller
Hersteller: Springer
Springer US
Springer US, New York, N.Y.
Modern Theoretical Chemistry
Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, D-69121 Heidelberg, juergen.hartmann@springer.com
Maße: 254 x 178 x 22 mm
Von/Mit: W. Miller
Erscheinungsdatum: 16.02.2013
Gewicht: 0,75 kg
Artikel-ID: 105321992